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Consumer/General Public and Livestock/Row Crop Producer
Air Handling Systems

Weapons of Mass Destruction (WMD) Prevention Task Force Information Paper

Summary

Release of a toxic chemical into an air handling system is a credible threat. Simple measures taken immediately on learning of the release might lessen harmful effects. Use of military and commercial chemical-biological detectors as "in-line" monitors is deemed unlikely to benefit because the response time is longer than the time needed for the toxic substance to be spread through the air handling system.

Key Findings

  • Most structures in the US have an air handling system (residences, office buildings, shopping centers, commercial establishments, transit systems, airports). Each system has one or more air intakes and a blower or some similar device that moves the air through the system (typically, the ventilation system).
     
  • Release of a toxic chemical into an air handling system is a credible threat because (1) toxic chemicals are readily available in quantities and in forms making them easy to disperse into the air handling system, (2) most air intakes are readily accessible, (3) few air handling systems have any in- line filters that would be effective at removing these chemicals, and (4) any release would be spread throughout the entire system within five minutes or less.
     
  • Release of a biological pathogen is a less credible threat because (1) the pathogens are difficult to obtain in the quantities and forms needed to mount an attack and (2) many pathogens would be knocked down by the "roughing" filter present in many air handling systems and by physical settling likely to occur within the ventilation system.
     
  • Military and commercial detection equipment is unlikely to benefit if used as an "in-line" monitor within the air handling system.
     
  • Benefits will be derived from the simple measures of (1) turning off the air handling system (for an external release) or opening up the air handling system to full outside make-up air (for an internal release) and (2) moving occupants away from windows, elevators, courtyards, and stairwells and into interior rooms.

Adversary's Capabilities: Hydrogen Cyanide (HCN)

Intelligence assessments have focused attention to hydrogen cyanide as a potential chemical weapon for use against, in particular, air handling systems (that is, released within a building or other confined space or introduced into an air intake such that the hydrogen cyanide is spread throughout the building or space via by air handling system). Fueling such assessments are open-literature reports of improvised devices involving compounds intended to evolve hydrogen cyanide gas on mixing.

  • The threat that hydrogen cyanide might be used against air handling systems is credible.
     
  • Hydrogen cyanide is a colorless liquid that rapidly evaporates under ordinary temperature and weather conditions. The hydrogen cyanide vapors (that is, a gas) have a faint almond odor; however, 20% of humans are incapable of detecting hydrogen cyanide at any concentration.
     
  • The toxicity of hydrogen cyanide is equivalent to that of chlorine but is significantly less than that of military chemical warfare agents. Hydrogen cyanide is less toxic by inhalation than by ingestion. The poisoning effects of hydrogen cyanide are not cumulative. An exposed person who survives can be expected to suffer no serious, long-term ill health effects from the hydrogen cyanide (by contrast, chlorine and many other toxic industrial chemicals often cause such long-term effects).
     
  • Factors working against use of hydrogen cyanide are
     
    • (1) the quantities required, with larger air handling systems requiring massive (multiple tank-car loads) quantities;
       
    • (2) the "lighter than air" quality of hydrogen cyanide, meaning the vapors rise and rapidly dissipate if the operational situation permits (as is the case in an open area or when the air handling system is turned to full outside make-up air);
       
    • (3) the relatively rapid biological turn-over of hydrogen cyanide, which means a human can tolerate a low dose over a long time with no or little ill health effects but will rapidly succumb to a massive, single dose (as is achieved in a "gas chamber"); and
       
    • (4) the rapid degradation of hydrogen cyanide to relatively non-toxic substances in the presence of water, such as the moisture in the air or from a water sprinkler system.
       
  • It is extremely difficult (some authorities report "impossible") to achieve a lethal concentration of hydrogen cyanide out-of-doors.
     
  • Factors working in favor of its use are
     
    • (1) its availability as liquid hydrogen cyanide, which has many legitimate industrial uses and
       
    • (2) the ability to make gaseous hydrogen cyanide "in-situ" by mixing a cyanide salt (such as sodium or potassium cyanide, which are available commercially) with certain acids (note: specifics have been omitted intentionally). Chlorine is a more readily available industrial chemical than is hydrogen cyanide. Devices for in-situ release of hydrogen cyanide can be neutralized with copious amounts of water, but the simplicity of such devices plus the ability to pre-position such devices make them a credible threat to air handling systems.

Preventions

  • Immediate, low- or no-cost measures:
     
    • Building and system managers (for example, subway and tunnel systems) should be instructed to cut off the air handling system immediately upon being advised of the release of a toxic substance external to the building. This simple measure will stop the spread of the toxic substance throughout the building.
       
    • Building and system managers should be instructed to place the air handling system on "full (or 100%) outside air" immediately upon being advised of the release of a toxic substance internal to the building. This simple measure will dilute the toxic substance already within the air handling system and will speed up its removal from the building.
       
    • Building occupants should be instructed to seek "shelter in place" in areas where air movement is low. Occupants should be instructed to stay away from windows and to avoid places where air movement is brisk (for example: elevator shafts and stairwells). Occupants should be instructed to remain inside, under cover.
       
    • Building and system managers should be advised that military and commercial detectors for toxic chemicals and biological pathogens are of little or no use as in-line monitors within an air handling system. The response time of currently available detectors is too slow to impact the spread of any toxic substance within the building or system. These detectors might have value as a diagnostic tool post-exposure of the building or system occupants and as a tool for determining when the outside air is safe for use following shut-off of external air intake.
       
    • Building and system managers should activate the water sprinklers if advised of an in-building release of hydrogen cyanide, chlorine or other toxic industrial chemicals. The water will mix with these chemicals to form less toxic substances, removing them from the air.
       
  • Near term measure:
     
    • Building and system managers should consider design and equipment modifications to make external air intakes less accessible. Options include installation of false or decoy intakes, camouflaging the actual intakes, and relocating the intakes to less accessible areas.

WMD Prevention Task Force Point of Contact

Benjamin C. Garrett
Chief Chemist
FBI Hazardous Materials Response Unit (HMRU)
Quantico, VA
Office: 703-632-4653
Pager: 888-771-6861

PaperNo. 2: Air Handling Systems
10-06-2001, Version
2

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Last Date Modified 10/22/2009
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